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Safety Data Sheet According to the Directive (EC) 1907/2006 (REACH)1. Identification of the Substance / Preparation and the Company / Undertaking
Article number:
KL1101-H, KL1101-H/0 Product identifier:
Dibenzoylperoxide in phthalic acid ester Relevant identified
uses advised against: Recommended use(s): hardener for reactive resins
Non-recommended use(s): None known. Supplier:
company FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Straße 5 Mobile: +49 4131 24445-0 Fax: +49 4131 24445-57 Emergency number: +49 4131 24445-0
2. Hazards Identification
This mixture is classified as hazardous according to CLP/GHS. Regulation (EC) No 1272/2008
Self-react. CD
Label Elements
Regulation (EC) No 1272/2008
Signal word:
GHS pictogram (e):
Hazard statement (e):
Heating may cause a fire. (H242) May cause an allergic skin reaction. (H317) Causes serious eye irritation. (H319) Very toxic to aquatic life. (H400) FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected] Precautionary Statement
Avoid breathing dust / fume / gas / mist / vapours / spray. (P261) Keep away from heat / sparks / open flames / hot surfaces. No smoking. (P210) Wear protective gloves / protective clothing / eye protection / face protection. (P280) Precautionary Statement
IF IN EYES: Rinse cautiously with water for several (Response):
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. (P305 + P351 + P338) Precautionary Statement
Store in a well-ventilated place. Keep cool. (P403 + (Storage):
Precautionary Statement
Dispose of contents / container in accordance with local (Disposal):
regulation. (P501) Hazardous component(s) for
contains dibenzoyl peroxide; benzoyl peroxide labelling:
Directive 67/548/EC or Directive 1999/45/EC
Labelling in accordance with directive 1999/45/EC:
requires labelling Hazardous component(s) for labelling:
contains dibenzoyl peroxide; benzoyl peroxide
Hazard symbol(s)
Dangerous for the environment. R-phrase(s)
Irritating to eyes. May cause sensitisation by skin contact. Very toxic to aquatic organisms. S-phrase(s)
Keep container tightly closed in a cool place. Keep away from reducing agents, heavy metal compounds, accelerators, acids and alkalis. Do not breathe dust. Wear suitable protective clothing, gloves and eye/face protection. Do not mix with accelerators or reducing agents. Do not empty into drains. FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected] 3. Composition / Information on Ingredients
Regulation (EC) No 1272/2008
EINECS-No.
Hazard class / Hazard
Component
REACH-No.
category / Hazard
statement
Self-react. B; H241 dibenzoyl peroxide; Skin Sens. 1; H317 benzoyl peroxide Eye Irrit. 2A; H319 Aquatic Acute 1; H400 dicyclohexyl phthalate Hazardous Ingredients as per Directive 67/548/EC or Directive 1999/45/EC
Component
Hazard symbol(s) / R-phrase(s)
dibenzoyl peroxide; benzoyl peroxide dicyclohexyl phthalate 4. First Aid Measures
General Advices
Medical treatment is necessary if symptoms are evidently caused by the effects on the skin, or the eyes, or by inhalation of its dust. Remove soiled, soaked clothing immediately. Inhalation:
In case of complaints get medical treatment. Eye contact:
Flush eyes thoroughly with a large amount of water and consult a physician. Skin contact:
Wash off with water and soap. If skin irritation occurs consult a physician. Ingestion:
Do not induce vomiting. Contact a doctor immediately. Most important symptoms and effects, both acute and delayed:
Skin sensitisation, skin irritation, causes eye irritation. FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected] 5. Fire-Fighting Measures
Extinguishing media:
Foam. Dry chemical. Carbon dioxide. Unsuitable extinguishing media
for safety reasons:
Advice for firefighters:
Wear self-contained breathing apparatus. Special hazards arising from the substance or mixture:
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of 6. Accidental Release Measures
Personal precautions,
Avoid dust formation. Use personal protective clothing. protective equipment and
Use breathing apparatus if exposed to vapours / dust / emergency procedures:
Environmental precautions:
Prevent product from getting into drains / surface water / groundwater. Methods and material for
Soak up material. Disposal according to regulations. containment and cleaning up:
Reference to other sections:
For personal protection see Section 8. 7. Handling and Storage
Precautions for Safe Handling
Safe handling advice:
Avoid dust formation. Keep container tightly closed. Do not return residues to the storage containers. Keep away from dirt, rust, chemicals, concentrated alkalis, concentrated acids, accelerators (e.g. heavy metal salts and amines). Advice on protection against fire
Take precautionary measures against static discharges. and explosion:
Avoid dust formation. In the event of fire, cool the endangered containers with water. Fire fighting must be carried out from a safe distance. Keep away from sources of ignition --- No smoking. Conditions for Safe Storage, Including any Incompatibilities
Requirements for storage areas
Protect from sun. Keep only in the original container at a and containers:
temperature not exceeding 25°C. FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected] 8. Exposure Controls / Personal Protection
Components or products of decomposition according to point 10, with limit values related to
the place of work which require monitoring
Ingredients
Limit values
Dibenzoyl peroxide 5mg/m³ WEL (long-term) 2009 Dicyclohexyl phthalate 84-61-7 5mg/m³ WEL (long-term) 2009
Exposure Controls
For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health Personal Protective Equipment
Respiratory protection:
Respiratory protection in case of dust formation, short term: filter appliance, filter P2. Eye protection:
Tightly fitting goggles. Hand protection:
Neoprene gloves. General Information: Gloves should be replaced regularly, especially after extended contact with the product. For each work- place a suitable glove type has to be selected. Skin and body protection:
On handling of larger quantities: face mask, chemical- resistant boots and apron. Hygiene measures:
Follow the usual good standards of occupational hygiene. Remove soiled or soaked clothing immediately. Store work clothing separately. Clean skin thoroughly after work; apply skin cream. General protective measures:
Do not breathe dust. Avoid contact with skin and eyes. 9. Physical and Chemical Properties
faint characteristic odour Melting temperature:
Boiling temperature:
not applicable (decomposition) Flash point:
Ignition temperature:
FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected] Lower explosion limit:
Upper explosion limit:
Vapour pressure:
Density:
1.23g/cm³ at 20°C Bulk density:
620 - 650kg/cm³ at 20°C
Water solubility:
Viscosity / dynamic:
Other information:
Dust explosions are generally to be expected with dust-forming organic products. 10. Stability and Reactivity
Reactivity:
see Section 10.2. Chemical stability:
Possibility of hazardous
Violent decomposition of the peroxide occurs on direct reactions:
contact with accelerators, e.g. heavy metal salts, tertiary amines, conc. mineral acids and alkali, and reducing agents. Vapours can form an explosive mixture with air. The product is normally supplied in a stabilised form. If the permissible storage period and / or storage temperature is exceeded, the product may polymerise with heat evolution. Conditions to avoid:
This material is considered stable under specified conditions of storage, shipment and / or use. Avoid high temperatures and sources of ignition. See Section 7, 'Handling and Storage', for specified conditions. Decomposes on heating. Incompatible materials:
Violent decomposition of the peroxide occurs on direct contact with accelerators, e.g. heavy metal salts, tertiary amines, conc. mineral acids and alkali, and reducing agents. Free radical initiators. Heavy metals. Hazardous decomposition
On thermal decomposition flammable and hazardous products:
vapours are formed. FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected] 11. Toxicological Information
Toxicokinetics, metabolism and
no specific test data available distribution:
Acute oral toxicity:
LD50 rat, > 2,000mg/kg Properties of components in summary Related to substance: product. Acute inhalation toxicity:
LC50 rat, > 24.3mg/l Related to substance: dibenzoyl peroxide Low toxicity by inhalation. Skin irritation / caustic burning:
Contact with skin may cause irritations. Properties of components in summary Related to substance: product Eye irritation / serious eye
Properties of components in summary Related to substance: product Irritating Eye irritant Category 2A (UN-GHS) Related to substance: dibenzoyl peroxide. Respiratory / skin sensitisation:
Guinea pig Bühler-test Sensitising Skin Sensitisation Category 1B (UN-GHS) Related to substance: dibenzoyl peroxide. Aspiration hazard:
Mutagenicity assessment:
not mutagenic in bacteria in vitro Related to substance: dibenzoyl peroxide. no specific test data available
Reprotoxicity / teratogenicity:
no specific test data available
Human health hazard assessment: CMR: no
Specific Target Organ Toxicity -
no specific test data available single exposure:
Specific Target Organ Toxicity -
no specific test data available repeated exposure:
General information:
There is no toxicological data available for the product as such. Carefully avoid skin and eye contact and inhalation of product dust. 12. Ecological Information
FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected] Toxicity
Hazardous to the aquatic
Acute aquatic toxicity category 1 (UN-GHS) environment:
Aquatoxicity, fish:
LC50 Species: guppy (Poecilia reticulata) Dose: 0.06mg/l Exposition time: 96h Related to substance: dibenzoyl peroxide. Aquatoxicity, invertebrates:
EC50 Species: Daphnia magna Dose: 0.11mg/l Exposition time: 48h Related to substance: dibenzoyl peroxide. Aquatoxicity, algae / aquatic
Species: Pseudokirchneriella subcapitata Dose: 0.06mg/l Exposition time: 72h Related to substance: dibenzoyl peroxide.
Persistence and Degradability
Persistence and degradability:
no evidence for hazardous properties
Biodegradability:
biodegradable properties of components in summary Related to substance: product. Bioaccumulative Potential
no specific test data available Mobility in Soil
Mobility:
no specific test data available Results of PBT and vPvB Assessment
PBT and vPvB assessment:
PBT: no vPvB: no Other Adverse Effects
General information:
Do not allow to enter soil, waterways or waste water. FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected] 13. Disposal Considerations:
Waste Treatment Methods
Product:
Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the disposal company in a suitable and licensed facility. Uncleaned packaging:
Contaminated packaging should be emptied optimally and after appropriate professional cleansing may be taken for reuse. Packaging that cannot be cleaned should be disposed of professionally. Uncontaminated packaging may be taken for recycling. Code of waste EWC:
08 04 09 Wastes from the manufacture, formulation, supply and use (MFSU) of adhesives and sealants (including waterproofing products) - waste adhesives and sealants containing organic solvents or other dangerous substances. Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities. 14. Transport Information
Land Transport
UN number:
Packaging group:
Hazard label:
5.2 (D), Environmentally hazardous Hazard number:
Proper shipping name:
ORGANIC PEROXIDE TYP D, SOLID Contains:
DIBENZOYL PEROXIDE UN number:
Packaging group:
Hazard label:
5.2 Environmentally hazardous Hazard number:
Proper shipping name:
ORGANIC PEROXIDE TYP D, SOLID Contains:
DIBENZOYL PEROXIDE FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected] Inland Waterway Transport
ADN (Germany): UN number:
Hazard label:
5.2 Environmentally Hazardous Proper shipping name:
ORGANIC PEROXIDE TYP D, SOLID Contains:
DIBENZOYL PEROXIDE Sea Transport
IMDG/GGVSea: UN number:
Packaging group:
Marine pollutant:
Proper shipping name:
ORGANIC PEROXIDE TYP D, SOLID Hazardous constituent:
(contains) DIBENZOYL PEROXIDE Air Transport
ICAO / IATA: UN number:
Packaging group:
Proper shipping name:
ORGANIC PEROXIDE TYP D, SOLID (contains) DIBENZOYL PEROXIDE Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
For transport approval see regulatory information. 15. Regulatory Information
Safety, health and environmental regulations/legislation specific for the substance or
National Legislation
Occupational restrictions:
Note for juveniles. Note for pregnant woman and nursing mothers (EC Directive 92/85/EEC). Status of registration:
REACH (EU) preregistered, registered or exempted TSCA (USA) listed or exempted DSL (CDN) listed or exempted AICS (AUS) listed or exempted METI (J) listed or exempted ECL (KOR) listed or exempted PICCS (RP) listed or exempted IECSC (CN) listed or exempted HSNO (NZ) listed or exempted. FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected] 16. Other Information
Relevant H phrases from chapter 3
dibenzoyl peroxide; benzoyl peroxide
Heating may cause a fire or explosion. May cause an allergic skin reaction. Causes serious eye irritation. Very toxic to aquatic life. R-phrases of relevance from chapter 3
Extreme risk of explosion by shock, friction, fire or other sources of ignition. Irritating to eyes. May cause sensitisation by skin contact. Very toxic to aquatic organisms. References
Relevant manuals and publications Own examinations Own toxicological and ecotoxicological studies Toxicological and ecotoxicological studies of other manufacturers SIAR RTK public files This information and all further technical advice is based on our present knowledge and experience. However, it implies no liability or other legal responsibility on our part, including with regard to existing third party intellectual property rights, especially patent rights. In particular, no warranty, whether expressed or implied, or guarantee of product properties in the legal sense is intended or implied. We reserve the right to make any changes according to technological progress or further developments. The customer is not released from the obligation to conduct careful inspection and testing of incoming goods. Performance of the product described herein should be verified by testing, which should be carried out only by qualified experts in the sole responsibility of a customer. Reference to trade names used by other companies is neither a recommendation, nor does it imply that similar products could not be used. FIOR & GENTZ Gesellschaft für Entwicklung und Vertrieb von orthopädietechnischen Systemen mbH Dorette-von-Stern-Str. 5 · D-21337 Lüneburg · +49 4131 24445-0 · +49 4131 24445-57 · www.fior-gentz.com · [email protected]
Source: http://www.fior-gentz.de/fileadmin/user_upload/pdf/SHDB/PD1101-KL_GB_Degaplast_Haerterpulver_Englisch.pdf
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